Inorganic Chemistry by Rajni Garg & Randhir Singh

Author:Rajni Garg & Randhir Singh
Language: eng
Format: azw3
Publisher: McGraw Hill
Published: 2015-02-15T05:00:00+00:00

(c) Iodine Oxide Fluorides Five iodine oxide fluorides of iodine are characterised. These are FIO2, F3IO, FIO3, F3IO2 and F5IO

(i) Iodine Dioxofluoride (FIO2) It is prepared by the direct fluorination of iodine pentoxide in anhydrous hydrogen fluoride at room temperature.

It is also prepared by the thermal dismutation of F3IO.

It is a colourless polymeric solid which decomposes above 200°C.

It undergoes alkaline hydrolysis and shows fluoride transfer reactions.

(ii) Iodine Oxotrifluoxide (F3IO) It is prepared by the treatment of IF5 with I2O5.

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